Messi struck twice as Barcelona inflicted more Champions League pain on Tottenham with a 4-2 win at Wembley on Wednesday, while Neymar hit a brilliant hat-trick in Paris Saint-Germain's 6-1 rout of Red Star Belgrade.
Philippe Coutinho scored after just two minutes for Barcelona, who arrived in London winless in three La Liga matches, with Ivan Rakitic drilling in a magnificent second.
Messi, who had earlier twice hit the post, then got on the scoresheet in between goals from Harry Kane and Erik Lamela, before the Argentina superstar grabbed his second late on to seal victory.
After a few bad results it was important to do well today. Our response was very good, said Barca coach Ernesto Valverde.
Barca head Group B on six points alongside Inter Milan, but Mauricio Pochettino's side face a vital double-header against PSV Eindhoven after failing to collect a point from their opening two matches.
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